The former Desperate Housewives star chaired the glitzy bash at the British capital's ME Hotel, where stars gathered for the fourth annual gala to bring in funds for a number of good causes, including the Eva Longoria Foundation and the Caudwell Children's charity.
During the event, the actress' close friend Beckham auctioned off a private dress fitting, while Scherzinger was presented with the 2013 Global Gift Philanthropist Award for her charity work.
Beckham took to her Twitter.com page to heap praise on her friend for organising the big night, writing, "So proud of Eva Longoria! Congratulations on a successful evening for the Global Gift Gala London."
Other stars in attendance included The Saturdays singer Vanessa White and pop star Pixie Lott, whose model boyfriend Oliver Cheshire hosted the gala.