The 70-year-old rocker was leaving a party thrown by designer Stella McCartney with the 'Armageddon' star and her actress friend, and the 40-year-old beauty was unimpressed when her dad asked the 'Mask' actress if he could take her out.
Asked if he'd ever hit on one of Liv's movie star friends during a game of 'Spill Your Guts or Fill Your Guts' with 'Late Late Show' host James Corden, Steven initially picked up a dried caterpillar to eat before deciding to be honest.
He admitted: ''Yes I have. And I got a lot of s**t for it too.''
He then told how he was seated next to Cameron - who is now married to Benji Madden - in a van on their way out of the bash and recalled: ''I look at this beautiful woman. I said, 'Cameron, should you ever need someone to take you to the movies or you know, like, if I was to, you know, ask you to show me around London...'
''And of course, Liv went, 'Daddy, you're hitting on my best girlfriend!' And I got ashamed for a moment.''
The Aerosmith frontman - who has been in rehab numerous times since 1983 - also admitted he's spent over $2 million on drugs.
Asked how much he's spent on drugs in his lifetime, he revealed: ''About $2 million. I snorted half of Peru.''
But the 'Crazy' hitmaker opted to chew a piece of cow intestine - which he spat out - rather than rank his bandmates ''in order of talent''.
He said: ''I got to go on tour with these guys. It's bad enough the s**t I say to them.''
Who are bassist Kyle Bann's biggest influences?
He's just dropped his latest single The Games Room.
On the South-East coast O'Hooley And Tidow treated the people of Deal to an evening of fabulous folk music.
Joep Beving's latest album 'Henosis' is an epic affair of more than twenty tracks and follows his 2018 release 'Conatus'.
Stronger Than Pride was released on this day (April 5) in 1988.
Everything you need to know about goth rock band Hana Piranha.
Aerosmith proved they are still as legendary as ever when they performed live at Donington...
For his lively film directing debut, Mike Myers (aka Austin Powers) traces the remarkable life...
Although this adventure's premise will appeal to children, and the child within us, the film...
Mary Katherine is a regular teenage girl who somehow mysteriously appears in an enchantingly beautiful...