The actors, who played Phoebe Buffay and Joey Tribbiani in the hit U.S. Tv sitcom, will reunite on the upcoming third series of Kudrow's Web Therapy nine years after Friends ended.
LeBlanc plays a gambler seeking help from Kudrow's therapist character Fiona Wallice, who takes up betting to help her new patient.
The show's creator Dan Bucatinsky tells E! Online, "(It's the) first time Lisa Kudrow and Matt LeBlanc will be onscreen together again since Friends. He plays a gambler and she becomes one, too. That's how good of a therapist she is. She helps him with addiction by becoming a gambler, too. It's awesome."
LeBlanc is the third Friends star to make an appearance on the show - Courteney Cox and David Schwimmer have also had guest spots.