Eva Longoria will reunite with her 'Desperate Housewives' co-star on 'Welcome To The Family'.

The 38-year-old actress will guest star on an upcoming episode of the NBC comedy, which stars Ricardo A Chavira, who played her husband Carlos Solis on the long running show, according to Deadline.

Eva revealed Ricardo personally asked her to guest star and she is ''very excited to be working with him again''.

Eva will play Ms Nunez, an English teacher who had a romantic relationship with her student's father before he was married.

Along with acting, Eva is known for her charity work and set up The Eva Longoria Foundation, which aims to help developmentally disabled children and women worldwide but particularly from the Latino community in the US.

The 38-year-old actress - whose parents are Mexican Americans - credits her ''curious'' personality for her desire to get involved with good causes.

She said: ''I'm curious by nature, energetic and ambitious. Ambition often provides much more success than talent or intelligence.

Eva has been married twice; first to 'General Hospital' star Tyler Christopher - who she separated from in 2004 - and then to French basketball player Tony Parker, but their union ended in divorce in 2010.